Calificación MotoGP - Gran Premio de España 2014
| Pos. | Piloto | Equipo | Moto | Tiempo |
|---|---|---|---|---|
| 1 | 
Marc Márquez |
Repsol Honda Team | Honda RC213V | 1:38.120 |
| 2 |
Jorge Lorenzo |
Movistar Yamaha MotoGP | Yamaha YZR-M1 | +0.421 |
| 3 |
Dani Pedrosa |
Repsol Honda Team | Honda RC213V | +0.510 |
| 4 | 
Valentino Rossi |
Movistar Yamaha MotoGP | Yamaha YZR-M1 | +0.737 |
| 5 |
Aleix Espargaró |
NGM Forward Racing | FTR Yamaha | +0.887 |
| 6 |
Andrea Dovizioso |
Ducati Team | Desmosedici GP14 | +1.102 |
| 7 | 
Stefan Bradl |
LCR Honda MotoGP | Honda RC213V | +1.123 |
| 8 |
Pol Espargaró |
Monster Yamaha Tech 3 | Yamaha YZR-M1 | +1.173 |
| 9 | 
Bradley Smith |
Monster Yamaha Tech 3 | Yamaha YZR-M1 | +1.270 |
| 10 |
Alvaro Bautista |
GO&FUN Honda Gresini | Honda RCV1000R | +1.631 |
| 11 | 
Colin Edwards |
NGM Forward Racing | FTR Yamaha | +1.694 |
| 12 |
Nicky Hayden |
Drive M7 Aspar | Honda RCV1000R | +1.706 |
| Q2 | ||||
| 1 |
Nicky Hayden |
Drive M7 Aspar | Honda RCV1000R | 1:39.427 |
| 2 |
Alvaro Bautista |
GO&FUN Honda Gresini | Honda RCV1000R | +0.168 |
| 3 | 
Hiroshi Aoyama |
Drive M7 Aspar | Honda RCV1000R | +0.341 |
| 4 | 
Cal Crutchlow |
Ducati Team | Desmosedici GP14 | +0.422 |
| 5 |
Andrea Iannone |
Pramac Racing | Ducati GP14 | +0.691 |
| 6 | 
Karel Abraham |
Cardion AB Motoracing | Honda RCV1000R | +0.699 |
| 7 |
Michele Pirro |
Ducati Team | Desmosedici GP14 | +0.812 |
| 8 |
Scott Redding |
GO&FUN Honda Gresini | Honda RCV1000R | +1.026 |
| 9 | 
Yonny Hernandez |
Energy T.I. Pramac Racing | Ducati | +1.139 |
| 10 |
Danilo Petrucci |
IodaRacing Project | ART | +1.582 |
| 11 |
Michael Laverty |
Paul Bird Motorsport | PBM Aprilia | +1.697 |
| 12 | 
Mike Di Meglio |
Avintia Racing | Kawasaki GP14 | +2.090 |
| 13 | 
Broc Parkes |
Paul Bird Motorsport | PBM Aprilia | +2.275 |
| 14 |
Héctor Barberá |
Avintia Racing | Kawasaki GP14 | +2.625 |